CAS OpenIR  > 中科院上海应用物理研究所2011-2018年
Selective Hydrogenation of CO2 to Ethanol over Cobalt Catalysts
Wang, LX; Wang, L; Zhang, J; Liu, XL; Wang, H; Zhang, W; Yang, Q; Ma, JY; Dong, X; Yoo, SJ; Kim, JG; Meng, XJ; Xiao, FS
2018
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN1433-7851
Volume57Issue:21Pages:6104-6108
Subtype期刊论文
AbstractMethods for the hydrogenation of CO2 into valuable chemicals are in great demand but their development is still challenging. Herein, we report the selective hydrogenation of CO2 into ethanol over non-noble cobalt catalysts (CoAlOx), presenting a significant advance for the conversion of CO2 into ethanol as the major product. By adjusting the composition of the catalysts through the use of different prereduction temperatures, the efficiency of CO2 to ethanol hydrogenation was optimized; the catalyst reduced at 600 8 gave an ethanol selectivity of 92.1% at 140 degrees C with an ethanol time yield of 0.444 mmolg(-1) h(-1). Operando FT-IR spectroscopy revealed that the high ethanol selectivity over the CoAlOx catalyst might be due to the formation of acetate from formate by insertion of *CHx, a key intermediate in the production of ethanol by CO2 hydrogenation.
KeywordFischer-tropsch Synthesis Methanol Synthesis Nanoparticles Alcohols Support Copper Fuel Rh
DOI10.1002/anie.201800729
Indexed BySCI
Language英语
WOS IDWOS:000432710100019
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/29127
Collection中科院上海应用物理研究所2011-2018年
Affiliation1.Wang, LX
2.Wang, L
3.Zhang, J
4.Liu, XL
5.Wang, H
6.Zhang, W
7.Yang, Q
8.Ma, JY
9.Dong, X
10.Yoo, SJ
11.Kim, JG
12.Meng, XJ
13.Xiao, FS
Recommended Citation
GB/T 7714
Wang, LX,Wang, L,Zhang, J,et al. Selective Hydrogenation of CO2 to Ethanol over Cobalt Catalysts[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(21):6104-6108.
APA Wang, LX.,Wang, L.,Zhang, J.,Liu, XL.,Wang, H.,...&Xiao, FS.(2018).Selective Hydrogenation of CO2 to Ethanol over Cobalt Catalysts.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(21),6104-6108.
MLA Wang, LX,et al."Selective Hydrogenation of CO2 to Ethanol over Cobalt Catalysts".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.21(2018):6104-6108.
Files in This Item: Download All
File Name/Size DocType Version Access License
Selective Hydrogenat(3104KB)期刊论文作者接受稿开放获取CC BY-NC-SAView Download
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Wang, LX]'s Articles
[Wang, L]'s Articles
[Zhang, J]'s Articles
Baidu academic
Similar articles in Baidu academic
[Wang, LX]'s Articles
[Wang, L]'s Articles
[Zhang, J]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Wang, LX]'s Articles
[Wang, L]'s Articles
[Zhang, J]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: Selective Hydrogenation of CO2 to Ethanol over Cobalt Catalysts.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.