Two-Dimensional AuMX2 (M = Al, Ga, In; X = S, Se) Monolayers Featuring Intracrystalline Aurophilic Interactions with Novel Electronic and Optical Properties
Wu, QS; Xu, WW; Ma, L; Wang, JL; Zeng, XC
2018
发表期刊ACS APPLIED MATERIALS & INTERFACES
ISSN1944-8244
卷号10期号:19页码:16739-16746
文章类型期刊论文
摘要Aurophilicity, known as aurophilic interaction, is a strong attractive van der Waals interaction between cationic gold(I) centers, whose strength is comparable to the hydrogen bond. Here, we show that aurophilicity can serve as an engineering approach to expand the structural dimensionality for nanomaterials design. Specifically, based on a global structure search method and density functional theory calculations, we predict a series of stable two-dimensional (2D) AuMX2 (M = Al, Ga, In; X = S, Se) structures featuring intracrystalline aurophilic interactions. All the AuMX2 monolayers designed are semiconductors with moderate band gaps, excellent carrier mobilities, and good optical properties. The intriguing chemistry of aurophilicity coupled with novel electronic properties render AuMX2 monolayers a potentially new series of 2D materials that are of fundamental importance in gold chemistry and of technological importance for nanoelectronics.
关键词Increase Structural Dimensionality Metal-metal Interactions Theoretical Chemistry Excited-state Solid-state Gold Localization Shell Luminescence Attraction
DOI10.1021/acsami.8b02820
收录类别SCI
语种英语
WOS记录号WOS:000432753800058
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/29201
专题中科院上海应用物理研究所2011-2018年
作者单位1.Wu, QS
2.Xu, WW
3.Ma, L
4.Wang, JL
5.Zeng, XC
推荐引用方式
GB/T 7714
Wu, QS,Xu, WW,Ma, L,et al. Two-Dimensional AuMX2 (M = Al, Ga, In; X = S, Se) Monolayers Featuring Intracrystalline Aurophilic Interactions with Novel Electronic and Optical Properties[J]. ACS APPLIED MATERIALS & INTERFACES,2018,10(19):16739-16746.
APA Wu, QS,Xu, WW,Ma, L,Wang, JL,&Zeng, XC.(2018).Two-Dimensional AuMX2 (M = Al, Ga, In; X = S, Se) Monolayers Featuring Intracrystalline Aurophilic Interactions with Novel Electronic and Optical Properties.ACS APPLIED MATERIALS & INTERFACES,10(19),16739-16746.
MLA Wu, QS,et al."Two-Dimensional AuMX2 (M = Al, Ga, In; X = S, Se) Monolayers Featuring Intracrystalline Aurophilic Interactions with Novel Electronic and Optical Properties".ACS APPLIED MATERIALS & INTERFACES 10.19(2018):16739-16746.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Wu, QS]的文章
[Xu, WW]的文章
[Ma, L]的文章
百度学术
百度学术中相似的文章
[Wu, QS]的文章
[Xu, WW]的文章
[Ma, L]的文章
必应学术
必应学术中相似的文章
[Wu, QS]的文章
[Xu, WW]的文章
[Ma, L]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。