CAS OpenIR  > 中科院上海应用物理研究所2011-2020年
Effects of cobalt carbide on Fischer-Tropsch synthesis with MnO supported Co-based catalysts
Sun, FF; Yang, RO; Xia, ZM; Yang, YQ; Zhao, Z; Gu, SQ; Wu, DS; Ding, YJ; Jiang, Z
2020
Source PublicationJOURNAL OF ENERGY CHEMISTRY
ISSN2095-4956
Volume42Pages:227-232
Subtype期刊论文
AbstractCobalt carbide (Co2C) was considered as potential catalysts available for large-scale industrialization of transforming syngas (H-2 and CO) to clean fuels. Herein, we successfully synthesized Co-based catalysts with MnO supported, to comprehend the effects of Co2C for Fischer-Tropsch synthesis (FTS) under ambient conditions. The huge variety of product selectivity which was contained by different active sites (Co and Co2C) has been found. Furthermore, density functional theory (DFT) shows that Co2C is efficacious of CO adsorption, whereas is weaker for H adsorption than Co. Combining the advantages of Co and Co2C, the catalyst herein can not only obtain more C5+ products but also suppress methane selectivity. It can be a commendable guide for the design of industrial application products in FTS. (C) 2019 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
KeywordHIGHER ALCOHOLS METHANE AROMATIZATION CARBON-MONOXIDE SELECTIVITY CONVERSION OLEFINS SYNGAS CELLULOSE SODIUM LA2O3
DOI10.1016/j.jechem.2019.07.007
Indexed BySCI ; EI
Language英语
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/32829
Collection中科院上海应用物理研究所2011-2020年
Affiliation1.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201204, Peoples R China
2.Chinese Acad Sci, Shanghai Adv Res Inst, Zhangjiang Lab, Shanghai Synchrotron Radiat Facil, Shanghai 201210, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100100, Peoples R China
4.Xi An Jiao Tong Univ, Ctr Appl Chem Res, Frontier Inst Sci & Technol, Xian 710049, Shaanxi, Peoples R China
5.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
6.Kyoto Univ, Grad Sch Sci, Sakyo Ku, Oiwake Cho, Kyoto, Kyoto 6068502, Japan
Recommended Citation
GB/T 7714
Sun, FF,Yang, RO,Xia, ZM,et al. Effects of cobalt carbide on Fischer-Tropsch synthesis with MnO supported Co-based catalysts[J]. JOURNAL OF ENERGY CHEMISTRY,2020,42:227-232.
APA Sun, FF.,Yang, RO.,Xia, ZM.,Yang, YQ.,Zhao, Z.,...&Jiang, Z.(2020).Effects of cobalt carbide on Fischer-Tropsch synthesis with MnO supported Co-based catalysts.JOURNAL OF ENERGY CHEMISTRY,42,227-232.
MLA Sun, FF,et al."Effects of cobalt carbide on Fischer-Tropsch synthesis with MnO supported Co-based catalysts".JOURNAL OF ENERGY CHEMISTRY 42(2020):227-232.
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