CAS OpenIR  > 中科院上海应用物理研究所2011-2020年
Structural Complexity and Magnetic Orderings in a Large Family of 3d-4f Heterobimetallic Sulfates
Lu, HJ; Diefenbach, K; Li, ZJ; Bao, HL; Guo, XF; Wang, JQ; Albrecht-Schmitt, TE; Lin, J
2020
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume59Issue:18Pages:13398-13406
Subtype期刊论文
AbstractThe synthesis of a large family of heterobimetallic lanthanide copper sulfates was realized via stoichiometric hydrothermal reactions among Ln(2)O(3), CuO, and H2SO4, giving rise to four distinct phases, namely Ln(2)Cu(SO4)(2)(OH)(4) (Ln = Sm-Ho) (LnCuSO(4)-1), Ln(4)Cu(SO4)(2)(OH)(10) (Ln = Tm-Lu) (LnCuSO(4)-2), LnCu(SO4)(OH)(3) (Ln = Nd-Gd, except Pm) (LnCuSO(4)-3), and LnCu(SO4)(OH)(3) (Ln = Dy-Lu) (LnCuSO(4)-4), with completely different topologies. The passage from LnCuSO(4)-1 and LnCuSO(4)-3 to LnCuSO(4)-2 and LnCuSO(4)-4 across the 4f series, respectively, can be ascribed to the effect of lanthanide contraction, which progressively induces shrinking of the Ln-O distance, reduction in the Ln coordination number, and eventually structural transitions. The incorporation of identical 3d-4f metal ions into different spin-lattices, in conjunction with substitution of diverse Ln(3+) cations within the same spin-lattice, gives rise to tunable magnetic properties varying from ferromagnetic ordering in GdCuSO4-3 and HoCuSO4-4 to antiferromagnetic ordering in YbCuSO4-4, and to paramagnetic correlations found in GdCuSO4-1 and YbCuSO4-2.
KeywordLANTHANIDE NI CO FRAMEWORKS TB MN LN
DOI10.1021/acs.inorgchem.0c01765
Indexed BySCI ; EI
Language英语
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Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/33155
Collection中科院上海应用物理研究所2011-2020年
Affiliation1.Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China
2.Univ Chinese Acad Sci, Shijingshan Dist, Beijing 100049, Peoples R China
3.Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA
4.Washington State Univ, Dept Chem, Washington, WA 99164 USA
5.Washington State Univ, Alexandra Navrotsky Inst Expt Thermodynam, Washington, WA 99164 USA
6.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
Recommended Citation
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Lu, HJ,Diefenbach, K,Li, ZJ,et al. Structural Complexity and Magnetic Orderings in a Large Family of 3d-4f Heterobimetallic Sulfates[J]. INORGANIC CHEMISTRY,2020,59(18):13398-13406.
APA Lu, HJ.,Diefenbach, K.,Li, ZJ.,Bao, HL.,Guo, XF.,...&Lin, J.(2020).Structural Complexity and Magnetic Orderings in a Large Family of 3d-4f Heterobimetallic Sulfates.INORGANIC CHEMISTRY,59(18),13398-13406.
MLA Lu, HJ,et al."Structural Complexity and Magnetic Orderings in a Large Family of 3d-4f Heterobimetallic Sulfates".INORGANIC CHEMISTRY 59.18(2020):13398-13406.
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