CAS OpenIR  > 中科院上海应用物理研究所2011-2020年
Sustainability Perspective-Oriented Synthetic Strategy for Zinc Single-Atom Catalysts Boosting Electrocatalytic Reduction of Carbon Dioxide and Oxygen
Wang, Nan1; Liu, Zhenhua1; Ma, Jingyuan3; Liu, Jingju1; Zhou, Peng6; Chao, Yuguang6; Ma, Chongbo1; Bo, Xiangjie1; Liu, Jian1; Hei, Yashuang1; Bi, Yanni1; Sun, Mimi1; Cao, Mengzhu1; Zhang, Hucai2; Chang, Fengqin2; Wang, Hsing-Lin4; Xu, Ping5; Hu, Zongqian7; Bai, Jing1; Sun, Hao1; Hu, Guangzhi2; Zhou, Ming1,4
2020
Source PublicationACS Sustainable Chemistry and Engineering
ISSN2168-0485
Volume8Issue:36Pages:13813-13822
Subtype期刊论文
AbstractGreen and sustainable electrochemical conversion and storage devices possess the nature to repress a negative effect on sustainability during energy conversion and storage. However, the sustainability of devices' components themselves (e.g., raw material abundance, eco-friendliness, and recycling) is often ignored, which may damage the environment and limit devices' practical applicability. Herein, guided by the concept of sustainability, a sustainable strategy is reported to synthesize the very cheap single zinc atoms dispersed on nitrogen-doped hierarchically porous carbon (SA-Zn-NHPC) with minimized environmental expense by employing abundant natural apples, natural egg whites, and relatively non-toxic ZnCl2 as raw materials. Theory calculations and experiments prove that Zn-N4 within SA-Zn-NHPC is responsible for superior CO2 reduction reaction (CO2RR) activity with high CO Faradaic efficiency (96%) at low overpotential (0.33 V) and outstanding O2 reduction reaction (ORR) activity with high half-wave potential (0.87 V) and high onset potential (1.00 V), which are among the best performance of single-atom catalysts. Additionally, remarkable activity and high stability of SA-Zn-NHPC for CO2RR and ORR as well as ultralow feedstock cost would render the recycling procedure for end-of-life catalysts (e.g., Pt within fuel cells) unrequired. The sustainability perspective-oriented strategy will bring major advances in both economical energy cost and environment protection. Copyright © 2020 American Chemical Society.
KeywordSustainable development Atoms Carbon dioxide Catalysts Chlorine compounds Doping (additives) Energy conversion Fuel cells Oxygen Oxygen reduction reaction Porous materials Recycling Reduction Toxic materials Virtual storage Zinc Zinc chloride Electrocatalytic reduction Electrochemical conversion Energy conversion and storages Environment protection Environmental expense Faradaic efficiencies Hierarchically porous carbons Sustainable strategies
DOI10.1021/acssuschemeng.0c05158
Indexed ByEI
Language英语
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/33180
Collection中科院上海应用物理研究所2011-2020年
Affiliation1.Key Laboratory of Polyoxometalate Science of Ministry of Education, National and Local United Engineering Laboratory for Power Batteries, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Department of Chemistry, Northeast Normal University, Jilin Province, Changchun; 130024, China;
2.Institute for Ecological Research and Pollution Control of Plateau Lakes, School of Ecology and Environmental Science, Yunnan University, Yunnan Province, Kunming; 650504, China;
3.Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai; 201204, China;
4.Guangdong Provincial Key Laboratory of Energy Materials for Electric Power, Department of Materials Science and Engineering, Southern University of Science and Technology, Guangdong Province, Shenzhen; 518055, China;
5.School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Heilongjiang Province, Harbin; 150001, China;
6.Department of Materials Science and Engineering, Beijing Innovation Center for Engineering Science and Advanced Technology, College of Engineering, Peking University, Beijing; 100871, China;
7.Beijing Institute of Radiation Medicine, Beijing; 100850, China
Recommended Citation
GB/T 7714
Wang, Nan,Liu, Zhenhua,Ma, Jingyuan,et al. Sustainability Perspective-Oriented Synthetic Strategy for Zinc Single-Atom Catalysts Boosting Electrocatalytic Reduction of Carbon Dioxide and Oxygen[J]. ACS Sustainable Chemistry and Engineering,2020,8(36):13813-13822.
APA Wang, Nan.,Liu, Zhenhua.,Ma, Jingyuan.,Liu, Jingju.,Zhou, Peng.,...&Zhou, Ming.(2020).Sustainability Perspective-Oriented Synthetic Strategy for Zinc Single-Atom Catalysts Boosting Electrocatalytic Reduction of Carbon Dioxide and Oxygen.ACS Sustainable Chemistry and Engineering,8(36),13813-13822.
MLA Wang, Nan,et al."Sustainability Perspective-Oriented Synthetic Strategy for Zinc Single-Atom Catalysts Boosting Electrocatalytic Reduction of Carbon Dioxide and Oxygen".ACS Sustainable Chemistry and Engineering 8.36(2020):13813-13822.
Files in This Item: Download All
File Name/Size DocType Version Access License
Sustainability Persp(4120KB)期刊论文出版稿开放获取CC BY-NC-SAView Download
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Wang, Nan]'s Articles
[Liu, Zhenhua]'s Articles
[Ma, Jingyuan]'s Articles
Baidu academic
Similar articles in Baidu academic
[Wang, Nan]'s Articles
[Liu, Zhenhua]'s Articles
[Ma, Jingyuan]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Wang, Nan]'s Articles
[Liu, Zhenhua]'s Articles
[Ma, Jingyuan]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: Sustainability Perspective-Oriented Synthetic Strategy for Zinc Single-Atom Catalysts Boosting Electrocatalytic Reduction of Carbon Dioxide and Oxygen.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.