Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| Sustainability Perspective-Oriented Synthetic Strategy for Zinc Single-Atom Catalysts Boosting Electrocatalytic Reduction of Carbon Dioxide and Oxygen | |
| Wang, Nan1; Liu, Zhenhua1; Ma, Jingyuan3; Liu, Jingju1; Zhou, Peng6; Chao, Yuguang6; Ma, Chongbo1; Bo, Xiangjie1; Liu, Jian1; Hei, Yashuang1; Bi, Yanni1; Sun, Mimi1; Cao, Mengzhu1; Zhang, Hucai2; Chang, Fengqin2; Wang, Hsing-Lin4; Xu, Ping5; Hu, Zongqian7; Bai, Jing1; Sun, Hao1; Hu, Guangzhi2; Zhou, Ming1,4 | |
| 2020 | |
| Source Publication | ACS Sustainable Chemistry and Engineering
 |
| ISSN | 2168-0485 |
| Volume | 8Issue:36Pages:13813-13822 |
| Subtype | 期刊论文 |
| Abstract | Green and sustainable electrochemical conversion and storage devices possess the nature to repress a negative effect on sustainability during energy conversion and storage. However, the sustainability of devices' components themselves (e.g., raw material abundance, eco-friendliness, and recycling) is often ignored, which may damage the environment and limit devices' practical applicability. Herein, guided by the concept of sustainability, a sustainable strategy is reported to synthesize the very cheap single zinc atoms dispersed on nitrogen-doped hierarchically porous carbon (SA-Zn-NHPC) with minimized environmental expense by employing abundant natural apples, natural egg whites, and relatively non-toxic ZnCl2 as raw materials. Theory calculations and experiments prove that Zn-N4 within SA-Zn-NHPC is responsible for superior CO2 reduction reaction (CO2RR) activity with high CO Faradaic efficiency (96%) at low overpotential (0.33 V) and outstanding O2 reduction reaction (ORR) activity with high half-wave potential (0.87 V) and high onset potential (1.00 V), which are among the best performance of single-atom catalysts. Additionally, remarkable activity and high stability of SA-Zn-NHPC for CO2RR and ORR as well as ultralow feedstock cost would render the recycling procedure for end-of-life catalysts (e.g., Pt within fuel cells) unrequired. The sustainability perspective-oriented strategy will bring major advances in both economical energy cost and environment protection. Copyright © 2020 American Chemical Society. |
| Keyword | Sustainable development Atoms Carbon dioxide Catalysts Chlorine compounds Doping (additives) Energy conversion Fuel cells Oxygen Oxygen reduction reaction Porous materials Recycling Reduction Toxic materials Virtual storage Zinc Zinc chloride Electrocatalytic reduction Electrochemical conversion Energy conversion and storages Environment protection Environmental expense Faradaic efficiencies Hierarchically porous carbons Sustainable strategies |
| DOI | 10.1021/acssuschemeng.0c05158 |
| Indexed By | EI |
| Language | 英语 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/33180 |
| Collection | 中科院上海应用物理研究所2011-2020年 |
| Affiliation | 1.Key Laboratory of Polyoxometalate Science of Ministry of Education, National and Local United Engineering Laboratory for Power Batteries, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Department of Chemistry, Northeast Normal University, Jilin Province, Changchun; 130024, China; 2.Institute for Ecological Research and Pollution Control of Plateau Lakes, School of Ecology and Environmental Science, Yunnan University, Yunnan Province, Kunming; 650504, China; 3.Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai; 201204, China; 4.Guangdong Provincial Key Laboratory of Energy Materials for Electric Power, Department of Materials Science and Engineering, Southern University of Science and Technology, Guangdong Province, Shenzhen; 518055, China; 5.School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Heilongjiang Province, Harbin; 150001, China; 6.Department of Materials Science and Engineering, Beijing Innovation Center for Engineering Science and Advanced Technology, College of Engineering, Peking University, Beijing; 100871, China; 7.Beijing Institute of Radiation Medicine, Beijing; 100850, China |
| Recommended Citation GB/T 7714 | Wang, Nan,Liu, Zhenhua,Ma, Jingyuan,et al. Sustainability Perspective-Oriented Synthetic Strategy for Zinc Single-Atom Catalysts Boosting Electrocatalytic Reduction of Carbon Dioxide and Oxygen[J]. ACS Sustainable Chemistry and Engineering,2020,8(36):13813-13822. |
| APA | Wang, Nan.,Liu, Zhenhua.,Ma, Jingyuan.,Liu, Jingju.,Zhou, Peng.,...&Zhou, Ming.(2020).Sustainability Perspective-Oriented Synthetic Strategy for Zinc Single-Atom Catalysts Boosting Electrocatalytic Reduction of Carbon Dioxide and Oxygen.ACS Sustainable Chemistry and Engineering,8(36),13813-13822. |
| MLA | Wang, Nan,et al."Sustainability Perspective-Oriented Synthetic Strategy for Zinc Single-Atom Catalysts Boosting Electrocatalytic Reduction of Carbon Dioxide and Oxygen".ACS Sustainable Chemistry and Engineering 8.36(2020):13813-13822. |
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| Sustainability Persp（4120KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | View Download | |
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