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Rheological properties of gamma irradiated [Me(3)NC(2)H(4)OH](+)[Zn(2)Cl(5)](-) and [Me(3)NC(2)H(4)OH](+)[Zn(3)Cl(7)](-) ionic liquids
Li, QM; Luo, YS; Wu, GZ(吴国忠); Chen, SM(陈仕谋); Wu, GZ (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China
2008
Source PublicationJOURNAL OF CENTRAL SOUTH UNIVERSITY OF TECHNOLOGY
ISSN1005-9784
Volume15Pages:145
AbstractThe objective of this work is to verify the rheological behavior of irradiated [Me(3)NC(2)H(4)OH]+[Zn(2)Cl(5)](-) and [Me(3)NC(2)H(4)OH](+)[ZN(3)Cl(7)](-) ionic liquids in comparison to the unirradiated ones, the viscosities were measured by a strain-control experiment under different irradiation doses' samples(0, 10, 20, 50, 100 kGy) at different shear rates and temperatures. The curves of shear stress against shear rate present that the viscosity of ionic liquid is insensitive to shear rate; the viscosity of ionic liquids decreases with increasing temperature, and can be fitted by Arrhenius equation very well. Gamma radiation causes a decrease of viscosity of [Me(3)NC(2)H(4)OH](+)[Zn(3)Cl(7)](-) by greater than 10%, but it does not impair the viscosity of [Me(3)NC(2)H(4)OH](+)[Zn(2)Cl(5)](-) (within the experimental error) except 20 kGy irradiated sample. The results show that the radiation stability of [Me(3)NC(2)H(4)OH](+)[Zn(2)Cl(5)](-) is higher than that of [Me(3)NC(2)H(4)OH](+)[Zn(3)Cl(7)](-).
Subject AreaBiotechnology & Applied Microbiology ; Science & Technology - Other Topics ; Materials Science
Indexed BySCI
Language英语
Funding Project应物所项目组
WOS IDWOS:000207591400033
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/7815
Collection中科院上海应用物理研究所2004-2010年
Corresponding AuthorWu, GZ (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China
Recommended Citation
GB/T 7714
Li, QM,Luo, YS,Wu, GZ,et al. Rheological properties of gamma irradiated [Me(3)NC(2)H(4)OH](+)[Zn(2)Cl(5)](-) and [Me(3)NC(2)H(4)OH](+)[Zn(3)Cl(7)](-) ionic liquids[J]. JOURNAL OF CENTRAL SOUTH UNIVERSITY OF TECHNOLOGY,2008,15:145.
APA Li, QM,Luo, YS,Wu, GZ,Chen, SM,&Wu, GZ .(2008).Rheological properties of gamma irradiated [Me(3)NC(2)H(4)OH](+)[Zn(2)Cl(5)](-) and [Me(3)NC(2)H(4)OH](+)[Zn(3)Cl(7)](-) ionic liquids.JOURNAL OF CENTRAL SOUTH UNIVERSITY OF TECHNOLOGY,15,145.
MLA Li, QM,et al."Rheological properties of gamma irradiated [Me(3)NC(2)H(4)OH](+)[Zn(2)Cl(5)](-) and [Me(3)NC(2)H(4)OH](+)[Zn(3)Cl(7)](-) ionic liquids".JOURNAL OF CENTRAL SOUTH UNIVERSITY OF TECHNOLOGY 15(2008):145.
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