CAS OpenIR  > 中科院上海原子核所2003年前
诱导效应指数与脂肪族胺、醇和醚的气相碱性
Alternative TitleRelationship between inductive effect index and gas phase basicity of aliphatic amine, alcohol and ether
张秀利,汪勇先,李俊玲
2003-02-25
Source Publication有机化学
ISSN0253-2786
Volume23Issue:2Pages:198-202
Abstract

用烷基诱导效应指数I和RX分子中质子亲合原子X所带电荷qx 及元素电负性XN 与脂肪胺、醇、醚的气相质子亲合能PA进行关联 .结果表明 ,脂肪胺、醇、醚的气相碱性可以用下式定量描述 PA (kJ·mol-1) =2 732 0 333-2 45 7 15 10∑I-14 92 2 35 1qx-732 62 77XN利用上式对 64种化合物的气相碱性进行预测 ,平均相对误差为 0 34 % ,预测值和实验值的偏差均在实验误差范围内

Language中文
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/7906
Collection中科院上海原子核所2003年前
Recommended Citation
GB/T 7714
张秀利,汪勇先,李俊玲. 诱导效应指数与脂肪族胺、醇和醚的气相碱性[J]. 有机化学,2003,23(2):198-202.
APA 张秀利,汪勇先,李俊玲.(2003).诱导效应指数与脂肪族胺、醇和醚的气相碱性.有机化学,23(2),198-202.
MLA 张秀利,汪勇先,李俊玲."诱导效应指数与脂肪族胺、醇和醚的气相碱性".有机化学 23.2(2003):198-202.
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