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| Co-60 gamma-initiated polymerization of vinyl monomers in room temperature ionic liquid/THF mixed solutions | |
| Liu, YD（刘耀东）; Wu, GZ（吴国忠）; Long, DW（龙德武）; Zhang, GR; Wu, GZ (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, POB 800-204, Shanghai 201800, Peoples R China | |
| 2005 | |
| Source Publication | POLYMER
 |
| ISSN | 0032-3861 |
| Volume | 46Issue:19Pages:8403 |
| Abstract | Radiation induced polymerization of styrene (St), methyl methacrylate (MMA) and n-butyl methacrylate (BMA) is carried out in a room temperature ionic liquid (RTIL), [Me3NC2H4OH](+)[ZnCl3](-) and in its mixed solutions with THF. The presence of ionic liquid (IL) leads to a significant increase in monomer conversion and polymer's molecular weight. Molecular weight distribution (MWD) of resulting polymer varies with the IL fraction in the RTIL/THF solutions and is also dependent on the monomer used. For polystyrene (PSt) and poly(n-butyl methacrylate) (PBMA), multi-modal broad MWD is observed at IL > 50 v% while single-modal narrow MWD is observed at IL < 40 v%. For poly(methyl methacrylate) (PMMA), however, nearly a single-modal MWD is observed at THF > 20 v%. The measured miscibility of polymer with RTIL is in the order: PMMA > PBMA > PSt. Here we propose that the difference in MWD is due to the inhomogeneous nature of the ionic liquid in micro-region and the immiscibility of polymer with medium. (c) 2005 Elsevier Ltd. All rights reserved. |
| Keyword | Room Temperature Ionic Liquid (Rtil) Radiation Polymerization |
| Subject Area | Physics |
| Indexed By | sci |
| Language | 英语 |
| Funding Project | 应物所项目组 |
| WOS ID | WOS:000231573100067 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/8021 |
| Collection | 中科院上海应用物理研究所2004-2010年 |
| Corresponding Author | Wu, GZ (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, POB 800-204, Shanghai 201800, Peoples R China |
| Recommended Citation GB/T 7714 | Liu, YD,Wu, GZ,Long, DW,et al. Co-60 gamma-initiated polymerization of vinyl monomers in room temperature ionic liquid/THF mixed solutions[J]. POLYMER,2005,46(19):8403. |
| APA | Liu, YD,Wu, GZ,Long, DW,Zhang, GR,&Wu, GZ .(2005).Co-60 gamma-initiated polymerization of vinyl monomers in room temperature ionic liquid/THF mixed solutions.POLYMER,46(19),8403. |
| MLA | Liu, YD,et al."Co-60 gamma-initiated polymerization of vinyl monomers in room temperature ionic liquid/THF mixed solutions".POLYMER 46.19(2005):8403. |
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