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Grafting of poly(tBA) and PtBA-b-PMMA onto the surface of SWNTs using carbanions as the initiator
Chen, SM(陈仕谋); Chen, DY(陈耀东); Wu, GZ(吴国忠); Chen, DY (reprint author), Fudan Univ, Dept Macromol Sci, Shanghai 200433, Peoples R China
2006
Source PublicationMACROMOLECULAR RAPID COMMUNICATIONS
ISSN1022-1336
Volume27Issue:11Pages:882
AbstractSoluble carbon nanotubes were prepared by treating SWNTs with sec-butyllithium and subsequently using the generated carbanions as the initiator to graft PtBA and PtBA-b-PMMA onto the surfaces of SWNTs. The anionic polymerization initiated by SWNTs-bearing carbanions not only provides a powerful strategy for functionalizing SWNTs but also gives us knowledge of the sidewall chemistry of SWNTs. The results indicate that a carbanion born on SWNTs behaves like an anionic initiator with high steric hindrance.
KeywordAnionic Polymerization Carbon Nanotubes Functionalization Graft Copolymers Initiators
Subject AreaChemistry
Indexed Bysci
Language英语
Funding Project应物所项目组
WOS IDWOS:000238504300011
Citation statistics
Cited Times:25[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/8064
Collection中科院上海应用物理研究所2004-2010年
Corresponding AuthorChen, DY (reprint author), Fudan Univ, Dept Macromol Sci, Shanghai 200433, Peoples R China
Recommended Citation
GB/T 7714
Chen, SM,Chen, DY,Wu, GZ,et al. Grafting of poly(tBA) and PtBA-b-PMMA onto the surface of SWNTs using carbanions as the initiator[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2006,27(11):882.
APA Chen, SM,Chen, DY,Wu, GZ,&Chen, DY .(2006).Grafting of poly(tBA) and PtBA-b-PMMA onto the surface of SWNTs using carbanions as the initiator.MACROMOLECULAR RAPID COMMUNICATIONS,27(11),882.
MLA Chen, SM,et al."Grafting of poly(tBA) and PtBA-b-PMMA onto the surface of SWNTs using carbanions as the initiator".MACROMOLECULAR RAPID COMMUNICATIONS 27.11(2006):882.
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