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Grafting of poly(tBA) and PtBA-b-PMMA onto the surface of SWNTs using carbanions as the initiator | |
Chen, SM(陈仕谋); Chen, DY(陈耀东); Wu, GZ(吴国忠); Chen, DY (reprint author), Fudan Univ, Dept Macromol Sci, Shanghai 200433, Peoples R China | |
2006 | |
Source Publication | MACROMOLECULAR RAPID COMMUNICATIONS
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ISSN | 1022-1336 |
Volume | 27Issue:11Pages:882 |
Abstract | Soluble carbon nanotubes were prepared by treating SWNTs with sec-butyllithium and subsequently using the generated carbanions as the initiator to graft PtBA and PtBA-b-PMMA onto the surfaces of SWNTs. The anionic polymerization initiated by SWNTs-bearing carbanions not only provides a powerful strategy for functionalizing SWNTs but also gives us knowledge of the sidewall chemistry of SWNTs. The results indicate that a carbanion born on SWNTs behaves like an anionic initiator with high steric hindrance. |
Keyword | Anionic Polymerization Carbon Nanotubes Functionalization Graft Copolymers Initiators |
Subject Area | Chemistry |
Indexed By | sci |
Language | 英语 |
Funding Project | 应物所项目组 |
WOS ID | WOS:000238504300011 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.sinap.ac.cn/handle/331007/8064 |
Collection | 中科院上海应用物理研究所2004-2010年 |
Corresponding Author | Chen, DY (reprint author), Fudan Univ, Dept Macromol Sci, Shanghai 200433, Peoples R China |
Recommended Citation GB/T 7714 | Chen, SM,Chen, DY,Wu, GZ,et al. Grafting of poly(tBA) and PtBA-b-PMMA onto the surface of SWNTs using carbanions as the initiator[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2006,27(11):882. |
APA | Chen, SM,Chen, DY,Wu, GZ,&Chen, DY .(2006).Grafting of poly(tBA) and PtBA-b-PMMA onto the surface of SWNTs using carbanions as the initiator.MACROMOLECULAR RAPID COMMUNICATIONS,27(11),882. |
MLA | Chen, SM,et al."Grafting of poly(tBA) and PtBA-b-PMMA onto the surface of SWNTs using carbanions as the initiator".MACROMOLECULAR RAPID COMMUNICATIONS 27.11(2006):882. |
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