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| High-yield synthesis of dimethyl carbonate from urea and methanol using a catalytic distillation process | |
| Wang, MH（王谋华）; Wang, H; Zhao, N; Wei, W; Sun, YH; Wang, MH (reprint author), Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China | |
| 2007 | |
| Source Publication | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| ISSN | 0888-5885 |
| Volume | 46Issue:9Pages:2683 |
| Abstract | Reaction equilibrium for the dimethyl carbonate (DMC) synthesis from urea and methanol was calculated based on the Benson method, and results showed that the reaction was thermodynamically unfavorable. In addition, urea methanolysis was conformed to be a consecutive reaction. Major side reactions in the DMC synthesis included the thermal decomposition of DMC and reaction between methyl carbamate (MC) and DMC, which reduced the DMC yield in the batch process. A catalytic distillation technique was proposed in this study to minimize the side reactions and unfavorable equilibrium for DMC synthesis. The DMC yield reached 60-70% in the catalytic distillation reactor over a Zn-based catalyst. |
| Subject Area | Physics |
| Indexed By | sci |
| Language | 英语 |
| Funding Project | 应物所项目组 |
| WOS ID | WOS:000245760300002 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/8072 |
| Collection | 中科院上海应用物理研究所2004-2010年 |
| Corresponding Author | Wang, MH (reprint author), Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China |
| Recommended Citation GB/T 7714 | Wang, MH,Wang, H,Zhao, N,et al. High-yield synthesis of dimethyl carbonate from urea and methanol using a catalytic distillation process[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2007,46(9):2683. |
| APA | Wang, MH,Wang, H,Zhao, N,Wei, W,Sun, YH,&Wang, MH .(2007).High-yield synthesis of dimethyl carbonate from urea and methanol using a catalytic distillation process.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,46(9),2683. |
| MLA | Wang, MH,et al."High-yield synthesis of dimethyl carbonate from urea and methanol using a catalytic distillation process".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 46.9(2007):2683. |
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