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On the mechanism of radiation-induced polymerization of vinyl monomers in ionic liquid
Liu, YD(刘耀东); Wu, GZ(吴国忠); Wu, GZ (reprint author), Chinese Acad Sci, Res Ctr Appl Radiat & Mat, Shanghai Inst Appl Phys, POB 800-204, Shanghai 201800, Peoples R China
2005
Source PublicationRADIATION PHYSICS AND CHEMISTRY
ISSN0969-806X
Volume73Issue:3Pages:159
AbstractAn attempt was made to investigate the mechanism controlling the radiation-induced polymerization of vinyl monomers in room temperature ionic liquids. For that purpose, copolymerization of styrene (St) and methyl methacrylate (MMA) was initiated by Co-60 gamma radiation in a moisture-stable ionic liquid, [choline chloride][ZnCl2], and its mixture with THF (4:1 v/v). By analyzing the product composition with FTIR for a series of poly(St-co-MMA) samples, it was found that the mole fraction of St in the copolymer is linearly proportional to the mole fraction of St in the feed. Therefore, radiation polymerization in ionic liquid and its mixture with organic solvent is suggested to be a radical propagating process. (c) 2004 Elsevier Ltd. All rights reserved.
KeywordIonic Liquid Radiation Polymerization Mechanism
Subject AreaPhysics
Indexed BySCI
Language英语
Funding Project应物所项目组
WOS IDWOS:000229354200005
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/8149
Collection中科院上海应用物理研究所2004-2010年
Corresponding AuthorWu, GZ (reprint author), Chinese Acad Sci, Res Ctr Appl Radiat & Mat, Shanghai Inst Appl Phys, POB 800-204, Shanghai 201800, Peoples R China
Recommended Citation
GB/T 7714
Liu, YD,Wu, GZ,Wu, GZ . On the mechanism of radiation-induced polymerization of vinyl monomers in ionic liquid[J]. RADIATION PHYSICS AND CHEMISTRY,2005,73(3):159.
APA Liu, YD,Wu, GZ,&Wu, GZ .(2005).On the mechanism of radiation-induced polymerization of vinyl monomers in ionic liquid.RADIATION PHYSICS AND CHEMISTRY,73(3),159.
MLA Liu, YD,et al."On the mechanism of radiation-induced polymerization of vinyl monomers in ionic liquid".RADIATION PHYSICS AND CHEMISTRY 73.3(2005):159.
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