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| On the mechanism of radiation-induced polymerization of vinyl monomers in ionic liquid | |
| Liu, YD（刘耀东）; Wu, GZ（吴国忠）; Wu, GZ (reprint author), Chinese Acad Sci, Res Ctr Appl Radiat & Mat, Shanghai Inst Appl Phys, POB 800-204, Shanghai 201800, Peoples R China | |
| 2005 | |
| Source Publication | RADIATION PHYSICS AND CHEMISTRY
 |
| ISSN | 0969-806X |
| Volume | 73Issue:3Pages:159 |
| Abstract | An attempt was made to investigate the mechanism controlling the radiation-induced polymerization of vinyl monomers in room temperature ionic liquids. For that purpose, copolymerization of styrene (St) and methyl methacrylate (MMA) was initiated by Co-60 gamma radiation in a moisture-stable ionic liquid, [choline chloride][ZnCl2], and its mixture with THF (4:1 v/v). By analyzing the product composition with FTIR for a series of poly(St-co-MMA) samples, it was found that the mole fraction of St in the copolymer is linearly proportional to the mole fraction of St in the feed. Therefore, radiation polymerization in ionic liquid and its mixture with organic solvent is suggested to be a radical propagating process. (c) 2004 Elsevier Ltd. All rights reserved. |
| Keyword | Ionic Liquid Radiation Polymerization Mechanism |
| Subject Area | Physics |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 应物所项目组 |
| WOS ID | WOS:000229354200005 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/8149 |
| Collection | 中科院上海应用物理研究所2004-2010年 |
| Corresponding Author | Wu, GZ (reprint author), Chinese Acad Sci, Res Ctr Appl Radiat & Mat, Shanghai Inst Appl Phys, POB 800-204, Shanghai 201800, Peoples R China |
| Recommended Citation GB/T 7714 | Liu, YD,Wu, GZ,Wu, GZ . On the mechanism of radiation-induced polymerization of vinyl monomers in ionic liquid[J]. RADIATION PHYSICS AND CHEMISTRY,2005,73(3):159. |
| APA | Liu, YD,Wu, GZ,&Wu, GZ .(2005).On the mechanism of radiation-induced polymerization of vinyl monomers in ionic liquid.RADIATION PHYSICS AND CHEMISTRY,73(3),159. |
| MLA | Liu, YD,et al."On the mechanism of radiation-induced polymerization of vinyl monomers in ionic liquid".RADIATION PHYSICS AND CHEMISTRY 73.3(2005):159. |
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