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Radiation degradation of Congo Red in aqueous solution | |
Ma, HJ(马红娟); Wang, M(王敏); Yang, RY; Wang, WF(王文锋); Zhao, J; Shen, ZQ; Yao, SD(姚思德); Wang, M (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, POB 800-204, Shanghai 201800, Peoples R China | |
2007 | |
Source Publication | CHEMOSPHERE
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ISSN | 0045-6535 |
Volume | 68Issue:6Pages:1098 |
Abstract | Radiation-induced degradation of Congo Red (an azo dye) in aqueous solution was studied both with steady-state radiolysis and time-resolve techniques of pulse radiolysis and laser flash photolysis. Decomposition and mineralization of Congo Red by gamma-rays was investigated with the changes of absorption spectra, degradation efficiency, TOC removal and pH changes of the solutions in different irradiation systems. The main radiolytic products resulting from steady-state radiolysis of Congo Red were examined by HPLC and LC-MS. Complete degradation of Congo Red was observed at different absorbed doses under diverse irradiation condition. The TOC removal of the solutions saturated with O-2 or N2O reached 76% and 86% at the absorbed dose of 11.9 kGy, respectively. Pulse radiolysis and laser flash photolysis experiments were carried out to study the reaction of Congo Red with e(aq)(-) and (OH)-O-center dot. The reaction rate constants were determined. (c) 2007 Elsevier Ltd. All rights reserved. |
Keyword | Gamma-rays Irradiation Degradation Toc Removal Pulse Radiolysis Laser Photolysis |
Subject Area | Physics |
Indexed By | SCI |
Language | 英语 |
Funding Project | 应物所项目组 |
WOS ID | WOS:000247389600013 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.sinap.ac.cn/handle/331007/8173 |
Collection | 中科院上海应用物理研究所2004-2010年 |
Corresponding Author | Wang, M (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, POB 800-204, Shanghai 201800, Peoples R China |
Recommended Citation GB/T 7714 | Ma, HJ,Wang, M,Yang, RY,et al. Radiation degradation of Congo Red in aqueous solution[J]. CHEMOSPHERE,2007,68(6):1098. |
APA | Ma, HJ.,Wang, M.,Yang, RY.,Wang, WF.,Zhao, J.,...&Wang, M .(2007).Radiation degradation of Congo Red in aqueous solution.CHEMOSPHERE,68(6),1098. |
MLA | Ma, HJ,et al."Radiation degradation of Congo Red in aqueous solution".CHEMOSPHERE 68.6(2007):1098. |
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