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Radiolysis and photolysis studies on active transient species of diethylstilbestrol | |
Dou, DY(窦大营); Liu, YB; Zhao, HW(赵红卫); Kong, L; Yao, SD(姚思德); Yao, SD (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China | |
2005 | |
Source Publication | JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
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ISSN | 1010-6030 |
Volume | 171Issue:3Pages:209 |
Abstract | Diethylstilbestrol (DES) is one of the most active estrogens in the environment. In this paper pulse radiolysis and laser flash photolysis studies were carried out to investigate mechanisms and dynamic characteristics of the transient species of DES produced by UV light and electron beam irradiations. The double bond between the benzene rings was supposed to be the most sensitive site attacked by hydroxyl radicals under high-energy electron beam irradiations. In laser flash photolysis DES was found to be either photoionized or excited by 248 nm laser to produce deprotonated radical cations and excited triplet states. It was found that DES could be degraded completely in oxygen- saturated aqueous solution under the UV lights. All the active species produced in pulse radiolysis and laser flash photolysis can cause environmental biologic effects. The work on degradation mechanisms of DES can be of help in finding ways to tackle the environmental DES problems. (c) 2004 Elsevier B.V. All rights reserved. |
Keyword | Diethylstilbestrol Radiolysis Photolysis |
Subject Area | Instruments & Instrumentation ; Nuclear Science & Technology ; Physics |
Indexed By | SCI |
Language | 英语 |
Funding Project | 应物所项目组 |
WOS ID | WOS:000228787400002 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.sinap.ac.cn/handle/331007/8178 |
Collection | 中科院上海应用物理研究所2004-2010年 |
Corresponding Author | Yao, SD (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China |
Recommended Citation GB/T 7714 | Dou, DY,Liu, YB,Zhao, HW,et al. Radiolysis and photolysis studies on active transient species of diethylstilbestrol[J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,2005,171(3):209. |
APA | Dou, DY,Liu, YB,Zhao, HW,Kong, L,Yao, SD,&Yao, SD .(2005).Radiolysis and photolysis studies on active transient species of diethylstilbestrol.JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,171(3),209. |
MLA | Dou, DY,et al."Radiolysis and photolysis studies on active transient species of diethylstilbestrol".JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY 171.3(2005):209. |
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