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Reactions of fullerenes with reactive methylene organophosphorus reagents: Efficient synthesis of organophosphorus group substituted C-60 and C-70 derivatives
Yin, JJ; Jin, LM; Liu, RL(刘瑞丽); Li, QN(李晴暖); Fan, CH(樊春海); Li, Y(李燕); Li, WX(李文新); Chen, QY; Li, WX (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China
2006
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
ISSN0022-3263
Volume71Issue:6Pages:2267
Abstract[GRAPHICS] Treatment of C-70 with cycloalkylaminomethylenebisphosphonates in the presence of NaH gave corresponding C-70 dimers 1 in good yield, while the methanofullerenes, C-70 > CH(PO3Et2) (3) and C-70 > C(PO3Et2)(2) (4) or C-60 > CH(PO3Et2) (5) and C-60 > C(PO3Et2)(2) (6), were obtained, respectively, by the reaction of C-70 of C-60 with tetraethyl methylenediphosphonate in the presence of NaH. Diethyl cyanornethylphosphonate reacted with C-60 of C-70 under similar conditions to afford C-60 > C(PO3Et2)CN (7) and C-70 > C(PO3Et2)CN (8). Furthermore, the presence of weak electronic interactions between two fullerene cages of fullerene dimers was demonstrated by cyclic voltammetry. A radical mechanism was proposed for the formation of the fullerene derivatives on the basis of the ESR studies.
Subject AreaChemistry
Indexed BySCI
Language英语
Funding Project应物所项目组
WOS IDWOS:000236307300009
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/8180
Collection中科院上海应用物理研究所2004-2010年
Corresponding AuthorLi, WX (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China
Recommended Citation
GB/T 7714
Yin, JJ,Jin, LM,Liu, RL,et al. Reactions of fullerenes with reactive methylene organophosphorus reagents: Efficient synthesis of organophosphorus group substituted C-60 and C-70 derivatives[J]. JOURNAL OF ORGANIC CHEMISTRY,2006,71(6):2267.
APA Yin, JJ.,Jin, LM.,Liu, RL.,Li, QN.,Fan, CH.,...&Li, WX .(2006).Reactions of fullerenes with reactive methylene organophosphorus reagents: Efficient synthesis of organophosphorus group substituted C-60 and C-70 derivatives.JOURNAL OF ORGANIC CHEMISTRY,71(6),2267.
MLA Yin, JJ,et al."Reactions of fullerenes with reactive methylene organophosphorus reagents: Efficient synthesis of organophosphorus group substituted C-60 and C-70 derivatives".JOURNAL OF ORGANIC CHEMISTRY 71.6(2006):2267.
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