Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
Fluorescence properties of C-60-Glucocorticoids | |
Liu, RL(刘瑞丽); Yin, JJ; Ma, JF; Li, QN; Li, WX(李文新); Li, WX (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China | |
2007 | |
Source Publication | SPECTROSCOPY AND SPECTRAL ANALYSIS
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ISSN | 1000-0593 |
Volume | 27Issue:6Pages:1161 |
Abstract | C-60 and its derivatives have become a research hotspot because of their unique structures, physical and chemical properties. The fluorescence properties of C-60 and its derivatives are an important research embranchment of the fullerene science field. In the present paper the fluorescence properties of C-60-glucocorticoids were firstly investigated. When excited with the wavelength of 350 nm at room temperature, C-60-glucocorticoids displayed the fluorescence emission in chloroform at 447 nm. The sixty carbon atoms of C-60 molecule are equivalent, belonging to the Ih group, and presenting high symmetry. It is difficult to observe the fluorescence of C-60 under the same condition because of the high symmetry of C-60 molecule. The fluorescence emission of C-60-glucocorticoids is probably due to the decrease in the high symmetry of C-60 molecule. Moreover, the fluorescence emission at 447 nm of a series of concentrations (10-13 mu mol center dot L-1) of C-60-glucocorticoids chloroform solutions excited at 350 nm was determined, and the result indicated that the C-60-glucocorticoids in chloroform could quench itself's fluorescence intensity. Within the concentration range of 10-64 mu mol center dot L-1, the fluorescence intensity increased along with the accretion of the concentration. When the concentration of C-60-glucocorticoids was greater than 64 mu mol center dot L-1 the fluorescence intensity decreased gradually. |
Keyword | C-60-glucocorticoids Fluorescence Properties Concentration Quenching Itself |
Subject Area | Life Sciences & Biomedicine - Other Topics ; Biophysics ; Radiology, Nuclear Medicine & Medical Imaging |
Indexed By | SCI |
Language | 英语 |
Funding Project | 应物所项目组 |
WOS ID | WOS:000248013200032 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.sinap.ac.cn/handle/331007/8285 |
Collection | 中科院上海应用物理研究所2004-2010年 |
Corresponding Author | Li, WX (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China |
Recommended Citation GB/T 7714 | Liu, RL,Yin, JJ,Ma, JF,et al. Fluorescence properties of C-60-Glucocorticoids[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2007,27(6):1161. |
APA | Liu, RL,Yin, JJ,Ma, JF,Li, QN,Li, WX,&Li, WX .(2007).Fluorescence properties of C-60-Glucocorticoids.SPECTROSCOPY AND SPECTRAL ANALYSIS,27(6),1161. |
MLA | Liu, RL,et al."Fluorescence properties of C-60-Glucocorticoids".SPECTROSCOPY AND SPECTRAL ANALYSIS 27.6(2007):1161. |
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