Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| Laser photolysis of ionic liquid [bmim][PF6] | |
| Zhu, GL（朱光来））; Wu, GZ（吴国忠）; Long, DW（龙德武）; Sha, ML（沙茂林）; Yao, S（姚思德）; Wu, GH (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China | |
| 2007 | |
| Source Publication | NUCLEAR SCIENCE AND TECHNIQUES
 |
| ISSN | 1001-8042 |
| Volume | 18Issue:1Pages:16 |
| Abstract | Photoinduced chemical reactions of 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]) were studied by laser photolysis at a wavelength of 266nm. Excited triplet state (3)[bn-dm](+)* was observed, radical cation [bmim](2+)* and neutral [bmim]* radical via photoionization were also formed. Energy transfer from (3)[bmim](+)* to beta-carotene was confirmed. Oxidation via one electron transfer from TMPD to (3)[bmim](+)* was also observed and the rate constant was determined to be 1.2 x 10(5) L.mol(-1).s(-1). The reaction of [bmim][PF6] with hydrated electron (e(aq)(-)) was confirmed by laser photolysis in aqueous solution. |
| Keyword | [Bmim][Pf6] Laser Flash Photolysis Triplet State Photoionization |
| Subject Area | Chemistry |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 应物所项目组 |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/8307 |
| Collection | 中科院上海应用物理研究所2004-2010年 |
| Corresponding Author | Wu, GH (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China |
| Recommended Citation GB/T 7714 | Zhu, GL,Wu, GZ,Long, DW,et al. Laser photolysis of ionic liquid [bmim][PF6][J]. NUCLEAR SCIENCE AND TECHNIQUES,2007,18(1):16. |
| APA | Zhu, GL,Wu, GZ,Long, DW,Sha, ML,Yao, S,&Wu, GH .(2007).Laser photolysis of ionic liquid [bmim][PF6].NUCLEAR SCIENCE AND TECHNIQUES,18(1),16. |
| MLA | Zhu, GL,et al."Laser photolysis of ionic liquid [bmim][PF6]".NUCLEAR SCIENCE AND TECHNIQUES 18.1(2007):16. |
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