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类胡萝卜素与二氧化氮自由基(NO_2~·)的反应 | |
赵文恩; 黄进勇; 王文峰; 钱素平; 姚思德 | |
2006 | |
Source Publication | 高等学校化学学报
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Issue | 3 |
Other Abstract | The interactions of carotenoids with NO·_ 2 were investigated by pulse radiolysis. Optical traces show bleaching of the ground-state absorption of β-carotene, zeaxanthin and canthaxanthin at 450 nm, and bixin at 460—510 nm. The transient absorption spectrum shows that the positive absorption attributed to the formation of carotenoid addition radicals cannot be observed in the range of 600—700 nm. It is suggested that carotenoids undergo more readily electron transfer with NO·_ 2 to yield the carotenoid radical cations. The rate constants for the reaction of β-carotene, zeaxanthin, bixin and canthaxanthin with NO·_ 2 obtained are 1.6×10 8, 2.41×10 8, 5.41×10 7 and 1.75×10 7 mol/(L -1·s -1), respectively. |
Keyword | 类胡萝卜素 No·2 脉冲辐解 瞬态吸收 |
Indexed By | CNKI |
Language | 中文 |
Funding Project | 应物所项目组 |
Document Type | 期刊论文 |
Identifier | http://ir.sinap.ac.cn/handle/331007/8505 |
Collection | 中科院上海应用物理研究所2004-2010年 |
Corresponding Author | 赵文恩 |
Recommended Citation GB/T 7714 | 赵文恩,黄进勇,王文峰,等. 类胡萝卜素与二氧化氮自由基(NO_2~·)的反应[J]. 高等学校化学学报,2006(3). |
APA | 赵文恩,黄进勇,王文峰,钱素平,&姚思德.(2006).类胡萝卜素与二氧化氮自由基(NO_2~·)的反应.高等学校化学学报(3). |
MLA | 赵文恩,et al."类胡萝卜素与二氧化氮自由基(NO_2~·)的反应".高等学校化学学报 .3(2006). |
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