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Effect of Nano-TiO2 Particles on the Performance of PVDF, PVDF-g-(Maleic anhydride), and PVDF-g-Poly(acryl amide) Membranes | |
Bian, Xiaokai(卞晓锴); Shi, Liuqing(施柳青); Yang, Xuanxuan(杨璇璇); Lu, Xiaofeng(陆晓峰) | |
2011 | |
Source Publication | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
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ISSN | 0888-5885 |
Volume | 50Issue:21Pages:12113 |
Abstract | To study the effects of nano-TiO2 particles on membrane performance and structure and to explore possible interactions between nano-TiO2 particles and polymer, polymer/TiO2 embedded hybrid membranes and neat polymer membranes were prepared using the phase inversion method. Poly(vinylidene difluoride) (PVDF) poly(vinylidene difluoride)-g-(maleic anhydride) (PVDF-g-MA), and poly(vinylidene difluoride)-g-poly(acryl amide) (PVDF-g-PAM) were selected as the membrane materials. SEM images showed that the hybrid membranes had a thinner skin layer and a larger number of pores in the sublayer than the neat membranes, which was the main cause of the increase in water flux of the hybrid membranes. They also exhibited a better antifouling property than the neat ones in the continuous BSA solution filtration process. In the 48 h-long pure water experiment, the hybrid membranes underwent a water flux decline and an increase in contact angle. The loss of nano-TiO2 particles, revealed by EDS analysis, influenced the stability of hybrid membrane performance. The XPS analysis suggested that nano-TiO2 particles were immobilized in the membrane surface layer through the formation of a stable chemical structure resulting from its reaction with polymer and/or through intertwining with polymer chains. |
Indexed By | SCI |
Language | 英语 |
Funding Project | 应物所项目组 |
WOS ID | WOS:000296128300037 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.sinap.ac.cn/handle/331007/9498 |
Collection | 中科院上海应用物理研究所2011-2020年 |
Recommended Citation GB/T 7714 | Bian, Xiaokai,Shi, Liuqing,Yang, Xuanxuan,et al. Effect of Nano-TiO2 Particles on the Performance of PVDF, PVDF-g-(Maleic anhydride), and PVDF-g-Poly(acryl amide) Membranes[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2011,50(21):12113. |
APA | Bian, Xiaokai,Shi, Liuqing,Yang, Xuanxuan,&Lu, Xiaofeng.(2011).Effect of Nano-TiO2 Particles on the Performance of PVDF, PVDF-g-(Maleic anhydride), and PVDF-g-Poly(acryl amide) Membranes.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,50(21),12113. |
MLA | Bian, Xiaokai,et al."Effect of Nano-TiO2 Particles on the Performance of PVDF, PVDF-g-(Maleic anhydride), and PVDF-g-Poly(acryl amide) Membranes".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 50.21(2011):12113. |
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