Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| SOLID-STATE REACTION BETWEEN P-BENZOQUINONE AND 4,4 '-BIPHENOL: A THz TIME-DOMAIN SPECTROSCOPIC STUDY | |
| Liu, Guifeng（刘桂锋）; Zhao, Hongwei（赵红卫）; Liu, Xiaohong; Wang, Wenfeng（王文锋） | |
| 2011 | |
| Source Publication | JOURNAL OF APPLIED SPECTROSCOPY
 |
| ISSN | 0021-9037 |
| Volume | 78Issue:3Pages:318 |
| Abstract | Terahertz time-domain spectroscopy (THz-TDS) was employed to record the progress of the reaction between p-benzoquinone (BQ) and 4,4'-biphenol (4BP) in the solid state. Through the THz-TDS, distinct absorption peaks of reactants and products were obtained. Sample preparations in the solid state, with and without grinding, influenced the conversion kinetics. Several kinetic equations or models were tried to fit the reaction data. A kinetic rate constant was obtained, with the reaction observed to be consistent with diffusion-controlled mechanisms. Differential scanning calorimetry and X-ray powder diffraction analyses were also used to characterize the solid-state reaction and products. The study shows that THz spectroscopy is a promising tool in evaluating the complex formation through solid-state reactions. |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 应物所项目组 |
| WOS ID | WOS:000294010700003 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/9590 |
| Collection | 中科院上海应用物理研究所2011-2019年 |
| Recommended Citation GB/T 7714 | Liu, Guifeng,Zhao, Hongwei,Liu, Xiaohong,et al. SOLID-STATE REACTION BETWEEN P-BENZOQUINONE AND 4,4 '-BIPHENOL: A THz TIME-DOMAIN SPECTROSCOPIC STUDY[J]. JOURNAL OF APPLIED SPECTROSCOPY,2011,78(3):318. |
| APA | Liu, Guifeng,Zhao, Hongwei,Liu, Xiaohong,&Wang, Wenfeng.(2011).SOLID-STATE REACTION BETWEEN P-BENZOQUINONE AND 4,4 '-BIPHENOL: A THz TIME-DOMAIN SPECTROSCOPIC STUDY.JOURNAL OF APPLIED SPECTROSCOPY,78(3),318. |
| MLA | Liu, Guifeng,et al."SOLID-STATE REACTION BETWEEN P-BENZOQUINONE AND 4,4 '-BIPHENOL: A THz TIME-DOMAIN SPECTROSCOPIC STUDY".JOURNAL OF APPLIED SPECTROSCOPY 78.3(2011):318. |
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